Selective ruthenium-catalyzed methylation of 2-arylethanols using methanol as C1 feedstock.

نویسندگان

  • Yang Li
  • Haoquan Li
  • Henrik Junge
  • Matthias Beller
چکیده

We describe the selective cross coupling of methanol and 2-arylethanols using a combination of Ru-MACHO (RuHCl(PNP(Ph))CO) and Shvo's diruthenium complex as catalysts. The desired domino transformation takes place via so-called borrowing hydrogen methodology, which constitutes an ideal example of green chemistry.

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عنوان ژورنال:
  • Chemical communications

دوره 50 95  شماره 

صفحات  -

تاریخ انتشار 2014